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Diastereoselective desymmetric 1,2-cis-glycosylation of meso-diols via chirality transfer from a glycosyl donor

Chemical desymmetrization reactions of meso-diols are highly effective for the precise and efficient synthesis of chiral molecules. However, even though enzyme-catalyzed desymmetric glycosylations are frequently found in nature, there is no method for highly diastereoselective desymmetric chemical g...

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Detalles Bibliográficos
Autores principales: Tanaka, Masamichi, Sato, Koji, Yoshida, Ryoki, Nishi, Nobuya, Oyamada, Rikuto, Inaba, Kazuki, Takahashi, Daisuke, Toshima, Kazunobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7229163/
https://www.ncbi.nlm.nih.gov/pubmed/32415161
http://dx.doi.org/10.1038/s41467-020-16365-8