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Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight

[Image: see text] We report a room-temperature protocol for the hydrogenation of various amides to produce amines and alcohols. Compared with most previous reports for this transformation, which use high temperatures (typically, 100–200 °C) and H(2) pressures (10–100 bar), this system proceeds under...

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Detalles Bibliográficos
Autores principales: Kar, Sayan, Rauch, Michael, Kumar, Amit, Leitus, Gregory, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7236134/
https://www.ncbi.nlm.nih.gov/pubmed/32455053
http://dx.doi.org/10.1021/acscatal.0c01406