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Roles of Salicylate Donors in Enhancement of Productivity and Isotacticity of Ziegler–Natta Catalyzed Propylene Polymerization

Roles of internal salicylate donors (SID) in enhancing activity and stereoselectivity of Ziegler–Natta catalyzed propylene (PP) polymerization were examined using DFT calculations. Five salicylate donors were studied. The chelate mode is the preferred adsorption mode. The linear relationship (R(2) =...

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Detalles Bibliográficos
Autores principales: Ratanasak, Manussada, Hasegawa, Jun-ya, Parasuk, Vudhichai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7240445/
https://www.ncbi.nlm.nih.gov/pubmed/32290323
http://dx.doi.org/10.3390/polym12040883