Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides

Ruthenocene-based PCP(tBu) pincer ligands were used to synthesize novel pincer palladium chloride Rc(F)[PCP(tBu)]PdCl (2a) and two novel palladium tetrahydroborates Rc(F)[PCP(tBu)]Pd(BH(4)) (3a) and Rc(*)[PCP(tBu)]Pd(BH(4)) (3b), where Rc(F)[PCP(tBu)] = κ(3)-{2,5-(tBu(2)PCH(2))(2-)C(5)H(2)}Ru(Cp(F))...

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Detalles Bibliográficos
Autores principales: Safronov, Sergey V., Osipova, Elena S., Nelyubina, Yulia V., Filippov, Oleg A., Barakovskaya, Irina G., Belkova, Natalia V., Shubina, Elena S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7248887/
https://www.ncbi.nlm.nih.gov/pubmed/32397552
http://dx.doi.org/10.3390/molecules25092236

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7248887/
https://www.ncbi.nlm.nih.gov/pubmed/32397552
http://dx.doi.org/10.3390/molecules25092236

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