Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

[Image: see text] The combination of photoredox catalysis with the Wolff–Kishner (WK) reaction allows the difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff–Kishner reaction). Photoredox initiated radical addition to N-sulfonylhydrazones yields α-functionalized...

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Detalles Bibliográficos
Autores principales: Wang, Shun, Cheng, Bei-Yi, Sršen, Matea, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7252948/
https://www.ncbi.nlm.nih.gov/pubmed/32233431
http://dx.doi.org/10.1021/jacs.0c00629

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7252948/
https://www.ncbi.nlm.nih.gov/pubmed/32233431
http://dx.doi.org/10.1021/jacs.0c00629

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