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Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions

Controlling the chemical glycosylation reaction remains the major challenge in the synthesis of oligosaccharides. Though 1,2-trans glycosidic linkages can be installed using neighboring group participation, the construction of 1,2-cis linkages is difficult and has no general solution. Long-range par...

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Detalles Bibliográficos
Autores principales: Hansen, Thomas, Elferink, Hidde, van Hengst, Jacob M. A., Houthuijs, Kas J., Remmerswaal, Wouter A., Kromm, Alexandra, Berden, Giel, van der Vorm, Stefan, Rijs, Anouk M., Overkleeft, Hermen S., Filippov, Dmitri V., Rutjes, Floris P. J. T., van der Marel, Gijsbert A., Martens, Jonathan, Oomens, Jos, Codée, Jeroen D. C., Boltje, Thomas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7260182/
https://www.ncbi.nlm.nih.gov/pubmed/32471982
http://dx.doi.org/10.1038/s41467-020-16362-x