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Desaturation via Redox-Neutral Hydrogen Transfer Process: Synthesis of 2-Allyl Anilines, Mechanism and Applications

An unprecedented desaturation method via redox-neutral hydrogen transfer process has been disclosed under mild conditions for the selective formation of terminal alkene with alkyl diazo compounds and aza-o-QMs. The control experiments and DFT calculations suggest that the visible light was introduce...

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Detalles Bibliográficos
Autores principales: Zheng, Yang, Dai, Ping, Gao, Dafang, Hong, Kemiao, Kou, Luyao, Dong, Shanliang, Hu, Jundie, Qiu, Lihua, Hu, Wenhao, Bao, Xiaoguang, Xu, Xinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7262561/
https://www.ncbi.nlm.nih.gov/pubmed/32480129
http://dx.doi.org/10.1016/j.isci.2020.101168