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Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides

[Image: see text] The introduction of (N(2))(3–•) radicals into multinuclear lanthanide molecular magnets raised hysteresis temperatures by stimulating strong exchange coupling between spin centers. Radical ligands with larger donor atoms could promote more efficient magnetic coupling between lantha...

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Detalles Bibliográficos
Autores principales: Goodwin, Conrad A. P., Réant, Benjamin L. L., Vettese, Gianni F., Kragskow, Jon G. C., Giansiracusa, Marcus J., DiMucci, Ida M., Lancaster, Kyle M., Mills, David P., Sproules, Stephen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7268190/
https://www.ncbi.nlm.nih.gov/pubmed/32421315
http://dx.doi.org/10.1021/acs.inorgchem.0c00470