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Ammonium bis­(salicyl­aldehyde thio­semi­car­ba­zonato)ferrate(III), a supra­molecular material containing low-spin Fe(III)

The synthesis and crystal structure (100 K) of the title com­pound, ammonium bis­[salicyl­aldehyde thio­semi­car­ba­zon­ato(2−)-κ(3) O,N (1),S]iron(III), NH(4)[Fe(C(8)H(7)N(3)OS)(2)], is reported. The asymmetric unit consists of an octa­hedral [Fe(III)(thsa)(2)](−) fragment, where thsa(2−) is salicy...

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Detalles Bibliográficos
Autores principales: Powell, Robyn E., Stöger, Berthold, Knoll, Christian, Müller, Danny, Weinberger, Peter, van Koningsbruggen, Petra J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273187/
https://www.ncbi.nlm.nih.gov/pubmed/32499461
http://dx.doi.org/10.1107/S2053229620006452