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Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na(2)(3-chlorobenzoate)(2)[12-MC(Mn(III)N(shi))-4](DMF)(6) and MnNa(3-chlorobenzoate)(3)[12-MC(Mn(III)N(shi))-4](DMF)(H(2)O)(4)·4DMF·0.72H(2)O
Similar synthetic schemes yield two different metallacrown (MC) complexes: bis(μ-3-chlorobenzoato)hexakis(dimethylformamide)tetrakis(μ(4)-N,2-dioxidobenzene-1-carboximidato)tetramanganese(III)disodium(I), [Mn(4)Na(2)(C(7)H(4)ClO(2))(2)(C(7)H(4)NO(3))(4)(C(3)H(7)NO)(6)] or Na(2)(3-chlorob...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7274016/ https://www.ncbi.nlm.nih.gov/pubmed/32523752 http://dx.doi.org/10.1107/S2056989020006362 |