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Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na(2)(3-chloro­benzoate)(2)[12-MC(Mn(III)N(shi))-4](DMF)(6) and MnNa(3-chloro­benzoate)(3)[12-MC(Mn(III)N(shi))-4](DMF)(H(2)O)(4)·4DMF·0.72H(2)O

Similar synthetic schemes yield two different metallacrown (MC) complexes: bis­(μ-3-chloro­benzoato)hexa­kis­(di­methyl­formamide)­tetra­kis­(μ(4)-N,2-dioxido­benzene-1-carboximidato)tetra­manganese(III)disodium(I), [Mn(4)Na(2)(C(7)H(4)ClO(2))(2)(C(7)H(4)NO(3))(4)(C(3)H(7)NO)(6)] or Na(2)(3-chloro­b...

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Detalles Bibliográficos
Autores principales: Zaleski, Curtis M., Zeller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7274016/
https://www.ncbi.nlm.nih.gov/pubmed/32523752
http://dx.doi.org/10.1107/S2056989020006362