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Influence of Vibrational Excitation on the Reaction of F(–) with CH(3)I: Spectator Mode Behavior, Enhancement, and Suppression

[Image: see text] Detailed insight into chemical reaction dynamics can be obtained by probing the effect of mode-specific vibrational excitation. Suppression or enhancement of reactivity is possible as is already known from the Polanyi rules. In the reaction F(–) + CH(3)I, we found vibrational enhan...

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Detalles Bibliográficos
Autores principales: Michaelsen, Tim, Bastian, Björn, Ayasli, Atilay, Strübin, Patrick, Meyer, Jennifer, Wester, Roland
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7277560/
https://www.ncbi.nlm.nih.gov/pubmed/32383877
http://dx.doi.org/10.1021/acs.jpclett.0c01095