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Influence of Vibrational Excitation on the Reaction of F(–) with CH(3)I: Spectator Mode Behavior, Enhancement, and Suppression
[Image: see text] Detailed insight into chemical reaction dynamics can be obtained by probing the effect of mode-specific vibrational excitation. Suppression or enhancement of reactivity is possible as is already known from the Polanyi rules. In the reaction F(–) + CH(3)I, we found vibrational enhan...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7277560/ https://www.ncbi.nlm.nih.gov/pubmed/32383877 http://dx.doi.org/10.1021/acs.jpclett.0c01095 |