Cargando…
A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties
Benzoxazine resin has been paid more attention in the fields of aviation, electronics, automobiles and new energy industries because of its excellent comprehensive performance. Further application is limited, however, by shortcomings such as high brittleness and high curing temperature. Furthermore,...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7284644/ https://www.ncbi.nlm.nih.gov/pubmed/32357390 http://dx.doi.org/10.3390/polym12050999 |
_version_ | 1783544515610542080 |
---|---|
author | Mei, Qilin Wang, Honghua Tong, Danliao Song, Jiuqiang Huang, Zhixiong |
author_facet | Mei, Qilin Wang, Honghua Tong, Danliao Song, Jiuqiang Huang, Zhixiong |
author_sort | Mei, Qilin |
collection | PubMed |
description | Benzoxazine resin has been paid more attention in the fields of aviation, electronics, automobiles and new energy industries because of its excellent comprehensive performance. Further application is limited, however, by shortcomings such as high brittleness and high curing temperature. Furthermore, higher thermal stability is imperiously demanded in special areas. Incorporating both an acetylene group and silicon into the benzoxazine monomer is a promising possible solution to improve the curing processability, thermal properties and toughness of benzoxazine. In this paper, an acetylene-functional/silicon-containing benzoxazine monomer was prepared by two-step synthesis, and acetylene-functional benzoxazine was also prepared as a comparison. FTIR and (1)H NMR confirmed the molecular structure of acetylene-functional/silicon-containing benzoxazine. Differential scanning calorimetry (DSC) analysis showed that the initial and peak degradation temperatures of acetylene-functional/silicon-containing benzoxazine were decreased by 21 °C and 18 °C compared with acetylene-functional benzoxazine, respectively. The apparent activation energy of the curing reaction of acetylene-functional/silicon-containing benzoxazine was 83.1 kJ/mol, which was slightly lower than acetylene-functional benzoxazine (84.7 kJ/mol). TGA results showed that the acetylene-functional/silicon-containing benzoxazine had a higher thermal stability than acetylene-functional benzoxazine. The temperatures of 5% weight loss of acetylene-functional/silicon-containing benzoxazine were 380 °C in nitrogen and 485 °C in air, and the char yield at 1000 °C was 80% in nitrogen and 21% in air, respectively. The results of mechanical properties showed that the impact strength of acetylene-functional/silicon-containing benzoxazine was higher than acetylene-functional benzoxazine by 35.4%. The tensile and flexural strengths of acetylene-functional/silicon-containing benzoxazine were slightly higher than that of acetylene-functional benzoxazine. |
format | Online Article Text |
id | pubmed-7284644 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-72846442020-06-15 A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties Mei, Qilin Wang, Honghua Tong, Danliao Song, Jiuqiang Huang, Zhixiong Polymers (Basel) Article Benzoxazine resin has been paid more attention in the fields of aviation, electronics, automobiles and new energy industries because of its excellent comprehensive performance. Further application is limited, however, by shortcomings such as high brittleness and high curing temperature. Furthermore, higher thermal stability is imperiously demanded in special areas. Incorporating both an acetylene group and silicon into the benzoxazine monomer is a promising possible solution to improve the curing processability, thermal properties and toughness of benzoxazine. In this paper, an acetylene-functional/silicon-containing benzoxazine monomer was prepared by two-step synthesis, and acetylene-functional benzoxazine was also prepared as a comparison. FTIR and (1)H NMR confirmed the molecular structure of acetylene-functional/silicon-containing benzoxazine. Differential scanning calorimetry (DSC) analysis showed that the initial and peak degradation temperatures of acetylene-functional/silicon-containing benzoxazine were decreased by 21 °C and 18 °C compared with acetylene-functional benzoxazine, respectively. The apparent activation energy of the curing reaction of acetylene-functional/silicon-containing benzoxazine was 83.1 kJ/mol, which was slightly lower than acetylene-functional benzoxazine (84.7 kJ/mol). TGA results showed that the acetylene-functional/silicon-containing benzoxazine had a higher thermal stability than acetylene-functional benzoxazine. The temperatures of 5% weight loss of acetylene-functional/silicon-containing benzoxazine were 380 °C in nitrogen and 485 °C in air, and the char yield at 1000 °C was 80% in nitrogen and 21% in air, respectively. The results of mechanical properties showed that the impact strength of acetylene-functional/silicon-containing benzoxazine was higher than acetylene-functional benzoxazine by 35.4%. The tensile and flexural strengths of acetylene-functional/silicon-containing benzoxazine were slightly higher than that of acetylene-functional benzoxazine. MDPI 2020-04-26 /pmc/articles/PMC7284644/ /pubmed/32357390 http://dx.doi.org/10.3390/polym12050999 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Mei, Qilin Wang, Honghua Tong, Danliao Song, Jiuqiang Huang, Zhixiong A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title | A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title_full | A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title_fullStr | A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title_full_unstemmed | A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title_short | A Novel Acetylene-Functional/Silicon-Containing Benzoxazine Resin: Preparation, Curing Kinetics and Thermal Properties |
title_sort | novel acetylene-functional/silicon-containing benzoxazine resin: preparation, curing kinetics and thermal properties |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7284644/ https://www.ncbi.nlm.nih.gov/pubmed/32357390 http://dx.doi.org/10.3390/polym12050999 |
work_keys_str_mv | AT meiqilin anovelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT wanghonghua anovelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT tongdanliao anovelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT songjiuqiang anovelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT huangzhixiong anovelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT meiqilin novelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT wanghonghua novelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT tongdanliao novelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT songjiuqiang novelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties AT huangzhixiong novelacetylenefunctionalsiliconcontainingbenzoxazineresinpreparationcuringkineticsandthermalproperties |