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The halogen bond with isocyano carbon reduces isocyanide odor

Predominantly, carbon atoms of various species function as acceptors of noncovalent interactions when they are part of a π-system. Here, we report on the discovery of a halogen bond involving the isocyano carbon lone pair. The co-crystallization or mechanochemical liquid-assisted grinding of model m...

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Detalles Bibliográficos
Autores principales: Mikherdov, Alexander S., Novikov, Alexander S., Boyarskiy, Vadim P., Kukushkin, Vadim Yu.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7286913/
https://www.ncbi.nlm.nih.gov/pubmed/32523100
http://dx.doi.org/10.1038/s41467-020-16748-x