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The halogen bond with isocyano carbon reduces isocyanide odor
Predominantly, carbon atoms of various species function as acceptors of noncovalent interactions when they are part of a π-system. Here, we report on the discovery of a halogen bond involving the isocyano carbon lone pair. The co-crystallization or mechanochemical liquid-assisted grinding of model m...
Autores principales: | Mikherdov, Alexander S., Novikov, Alexander S., Boyarskiy, Vadim P., Kukushkin, Vadim Yu. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7286913/ https://www.ncbi.nlm.nih.gov/pubmed/32523100 http://dx.doi.org/10.1038/s41467-020-16748-x |
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