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Concise and Practical Total Synthesis of (+)-Abscisic Acid

[Image: see text] (+)-Abscisic acid 1 was obtained in a concise total synthesis from ethyl 2,6,6-trimethyl-4-oxocyclohex-2-ene-1-carboxylate (2) with 41% overall yield in seven steps. A hydroxyl group was stereoselectively introduced by Sharpless asymmetric epoxidation; then, the side chain was appe...

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Detalles Bibliográficos
Autores principales: Kim, Dahye, Koo, Sangho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7288699/
https://www.ncbi.nlm.nih.gov/pubmed/32548516
http://dx.doi.org/10.1021/acsomega.0c01332