Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Ferrocenyl thioketones reacted with donor–acceptor cyclopropanes in dichloromethane at room temperature in the presence of catalytic amounts of Sc(OTf)(3) yielding tetrahydrothiophene derivatives, products of formal [3 + 2]-cycloaddition reactions, in moderate to high yields. In all studied cases, d...

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Detalles Bibliográficos
Autores principales: Mlostoń, Grzegorz, Kowalczyk, Mateusz, Augustin, André U, Jones, Peter G, Werz, Daniel B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://www.ncbi.nlm.nih.gov/pubmed/32566031
http://dx.doi.org/10.3762/bjoc.16.109

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7296194/
https://www.ncbi.nlm.nih.gov/pubmed/32566031
http://dx.doi.org/10.3762/bjoc.16.109

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