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Ruthenium 4d-to-2p X-ray Emission Spectroscopy: A Simultaneous Probe of the Metal and the Bound Ligands

[Image: see text] Ruthenium 4d-to-2p X-ray emission spectroscopy (XES) was systematically explored for a series of Ru(2+) and Ru(3+) species. Complementary density functional theory calculations were utilized to allow for a detailed assignment of the experimental spectra. The studied complexes have...

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Detalles Bibliográficos
Autores principales: Levin, Natalia, Peredkov, Sergey, Weyhermüller, Thomas, Rüdiger, Olaf, Pereira, Nilson B., Grötzsch, Daniel, Kalinko, Aleksandr, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7298721/
https://www.ncbi.nlm.nih.gov/pubmed/32390417
http://dx.doi.org/10.1021/acs.inorgchem.0c00663