Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications

[Image: see text] The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir[(dF(CF(3))ppy)(2)(dtbbpy)]PF(6) or fac-Ir(ppy)(3) is reported. Mechanistic studies indicate that a radical chain mechanism operates, which proceeds via a phosphoranyl radical generated from...

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Detalles Bibliográficos
Autores principales: Clarke, Aimee K., Parkin, Alison, Taylor, Richard J. K., Unsworth, William P., Rossi-Ashton, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7304878/
https://www.ncbi.nlm.nih.gov/pubmed/32582464
http://dx.doi.org/10.1021/acscatal.0c00690

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7304878/
https://www.ncbi.nlm.nih.gov/pubmed/32582464
http://dx.doi.org/10.1021/acscatal.0c00690

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