Efficient Stereoselective Carbocyclization to cis-1,4-Disubstituted Heterocycles Enabled by Dual Pd/Electron Transfer Mediator (ETM) Catalysis

[Image: see text] An efficient Pd/ETM (ETM = electron transfer mediator)-cocatalyzed stereoselective oxidative carbocyclization of dienallenes under aerobic oxidation conditions has been developed to afford six-membered heterocycles. The use of a bifunctional cobalt complex [Co(salophen)-HQ] as hybr...

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Detalles Bibliográficos
Autores principales: Zhu, Can, Liu, Jie, Mai, Binh Khanh, Himo, Fahmi, Bäckvall, Jan-E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7307908/
https://www.ncbi.nlm.nih.gov/pubmed/32101690
http://dx.doi.org/10.1021/jacs.9b13700

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7307908/
https://www.ncbi.nlm.nih.gov/pubmed/32101690
http://dx.doi.org/10.1021/jacs.9b13700

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