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Highly selective Diels–Alder and Heck arylation reactions in a divergent synthesis of isoindolo- and pyrrolo-fused polycyclic indoles from 2-formylpyrrole

A highly regio-, chemo- and stereoselective divergent synthesis of isoindolo- and pyrrolo-fused polycyclic indoles is herein described, starting from 2-formylpyrrole and employing Diels–Alder and Heck arylation reactions. 3-(N-Benzyl-2-pyrrolyl)acrylates and 4-(pyrrol-2-yl)butenones underwent a high...

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Detalles Bibliográficos
Autores principales: Escalante, Carlos H, Martínez-Mora, Eder I, Espinoza-Hicks, Carlos, Camacho-Dávila, Alejandro A, Ramos-Morales, Fernando R, Delgado, Francisco, Tamariz, Joaquín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7308616/
https://www.ncbi.nlm.nih.gov/pubmed/32595780
http://dx.doi.org/10.3762/bjoc.16.113