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Direct Measurement of Radical-Catalyzed C(6)H(6) Formation from Acetylene and Validation of Theoretical Rate Coefficients for C(2)H(3) + C(2)H(2) and C(4)H(5) + C(2)H(2) Reactions
[Image: see text] The addition of vinylic radicals to acetylene is an important step contributing to the formation of polycyclic aromatic hydrocarbons in combustion. The overall reaction 3C(2)H(2) → C(6)H(6) could result in large benzene yields, but without accurate rate parameters validated by expe...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7309326/ https://www.ncbi.nlm.nih.gov/pubmed/32164407 http://dx.doi.org/10.1021/acs.jpca.0c00558 |