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Direct Measurement of Radical-Catalyzed C(6)H(6) Formation from Acetylene and Validation of Theoretical Rate Coefficients for C(2)H(3) + C(2)H(2) and C(4)H(5) + C(2)H(2) Reactions

[Image: see text] The addition of vinylic radicals to acetylene is an important step contributing to the formation of polycyclic aromatic hydrocarbons in combustion. The overall reaction 3C(2)H(2) → C(6)H(6) could result in large benzene yields, but without accurate rate parameters validated by expe...

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Detalles Bibliográficos
Autores principales:	Smith, Mica C., Liu, Guozhu, Buras, Zachary J., Chu, Te-Chun, Yang, Jeehyun, Green, William H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7309326/ https://www.ncbi.nlm.nih.gov/pubmed/32164407 http://dx.doi.org/10.1021/acs.jpca.0c00558

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