Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic Os(VI)N–Pt(II) Complex

[Image: see text] Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouch...

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Detalles Bibliográficos
Autores principales: Reinholdt, Anders, Alemayehu, Abraham B., Gagnon, Kevin J., Bendix, Jesper, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7311052/
https://www.ncbi.nlm.nih.gov/pubmed/32227864
http://dx.doi.org/10.1021/acs.inorgchem.0c00654

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7311052/
https://www.ncbi.nlm.nih.gov/pubmed/32227864
http://dx.doi.org/10.1021/acs.inorgchem.0c00654

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