Cargando…

Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic Os(VI)N–Pt(II) Complex

[Image: see text] Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouch...

Descripción completa

Detalles Bibliográficos
Autores principales:	Reinholdt, Anders, Alemayehu, Abraham B., Gagnon, Kevin J., Bendix, Jesper, Ghosh, Abhik
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7311052/ https://www.ncbi.nlm.nih.gov/pubmed/32227864 http://dx.doi.org/10.1021/acs.inorgchem.0c00654

Ejemplares similares

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex
por: Xiang, Jing, et al.
Publicado: (2021)

Carbide complexes as π-acceptor ligands
por: Reinholdt, Anders, et al.
Publicado: (2015)

The nature of metal–metal bonding in Re-, Ru- and Os-corrole dimers
por: Obies, Mohammed, et al.
Publicado: (2022)

Thermodynamic and reactivity studies of a tin corrole–cobalt porphyrin heterobimetallic complex
por: Wang, Zikuan, et al.
Publicado: (2018)

Osmium and OsO (x) nanoparticles: an overview of syntheses and applications
por: Quinson, Jonathan
Publicado: (2022)

A Breast Cancer Stem Cell-Selective, Mammospheres-Potent Osmium(VI) Nitrido Complex
por: Suntharalingam, Kogularamanan, et al.
Publicado: (2014)

OsB(9) (−): An Aromatic Osmium-Centered Monocyclic Boron Ring
por: Yu, Rui, et al.
Publicado: (2021)

Rhenium-Imido Corroles
por: Alemayehu, Abraham B., et al.
Publicado: (2020)

Neutron physics of the Re/Os clock. 1. Measurement of the (n, gamma) cross sections of Os-186, Os-187, Os-188 at the CERN n_TOF facility
por: Mosconi, M, et al.
Publicado: (2010)

Exploring the Association of Electron‐Donating Corroles with Phthalocyanines as Electron Acceptors
por: Platzer, Benedikt, et al.
Publicado: (2022)

Dinuclear nitrido-bridged osmium complexes inhibit the mitochondrial calcium uniporter and protect cortical neurons against lethal oxygen–glucose deprivation
por: Woods, Joshua J., et al.
Publicado: (2022)

Neutron physics of the Re/Os clock. 3. Resonance analyses and stellar (n, gamma) cross sections of Os-186, Os-187, Os-188
por: Fujii, K, et al.
Publicado: (2010)

Measurements of the $(n,\gamma)$ and (n,n') reaction cross sections on $^{186,187,189}Os$ and $^{187}Re-^{187}Os$ cosmochronology
por: Segawa, M, et al.
Publicado: (2006)

BUFFERED OSMIUM TETROXIDE (OsO(4)) FIXATION FOR CYTOLOGICAL AND FEULGEN MICROSPECTROPHOTOMETRIC STUDIES OF HUMAN RECTAL POLYPS
por: Leuchtenberger, Cecilie, et al.
Publicado: (1955)

NMR studies of group 8 metallodrugs: (187)Os-enriched organo-osmium half-sandwich anticancer complex
por: Needham, Russell J., et al.
Publicado: (2021)

High‐Spin Iron(VI), Low‐Spin Ruthenium(VI), and Magnetically Bistable Osmium(VI) in Molecular Group 8 Nitrido Trifluorides NMF(3)
por: Stüker, Tony, et al.
Publicado: (2021)

Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems
por: Chen, Shiyan, et al.
Publicado: (2020)

Osmium Atoms and Os(2) Molecules Move Faster on Selenium-Doped Compared to Sulfur-Doped Boronic Graphenic Surfaces
por: Barry, Nicolas P. E., et al.
Publicado: (2015)

Mineral separation protocol for accurate and precise rhenium-osmium (Re-Os) geochronology and sulphur isotope composition of individual sulphide species
por: Saintilan, N.J., et al.
Publicado: (2020)

Catalyst-Free Formal Conjugate Addition/Aldol or Mannich Multicomponent Reactions of Mixed Aliphatic Organozinc Reagents, π-Electrophiles and Michael Acceptors
por: Pinaud, Marine, et al.
Publicado: (2023)

Synthesis and characterization of meso-substituted A(2)B corroles with extended π-electronic structure
por: Haas, Michael, et al.
Publicado: (2017)

Iridium(VII)–Corrole Terminal Carbides Should Exist as Stable Compounds
por: Conradie, Jeanet, et al.
Publicado: (2021)

Synthesis and molecular structure of perhalogenated rhenium-oxo corroles
por: Alemayehu, Abraham B., et al.
Publicado: (2020)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

X-ray absorption spectroscopy of archetypal chromium porphyrin and corrole derivatives
por: Cao, Rui, et al.
Publicado: (2020)

Regioselective thiocyanation of corroles and the synthesis of gold nanoparticle–corrole assemblies
por: Sahu, Kasturi, et al.
Publicado: (2019)

Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
por: Guo, Ruizhi, et al.
Publicado: (2017)

Simple, Axial Ligand-Mediated Route to Water-Soluble Iridium Corroles
por: Thomassen, Ivar K., et al.
Publicado: (2021)

OS X and iOS Kernel Programming
por: Halvorsen, Ole Henry, et al.
Publicado: (2011)

Case of Caries of the Os Coronary and Os Pedis
por: Soula, William
Publicado: (1880)

Reaction of Corroles with Sarcosine and Paraformaldehyde: A New Facet of Corrole Chemistry
por: Barata, Joana F. B., et al.
Publicado: (2022)

“N‐π‐N” Type Oligomeric Acceptor Achieves an OPV Efficiency of 18.19% with Low Energy Loss and Excellent Stability
por: Zhang, Lili, et al.
Publicado: (2022)

Pages, keynote & numbers for OS X and iOS
por: Spivey, Dwight
Publicado: (2014)

iOS and OS X network programming cookbook
por: Hoffman, Jon
Publicado: (2014)

Learn C on the Mac: for OS X and iOS
por: Mark, Dave, et al.
Publicado: (2012)

(188)Re(V) Nitrido Radiopharmaceuticals for Radionuclide Therapy
por: Boschi, Alessandra, et al.
Publicado: (2017)

An image and text-based multimodal model for detecting fake news in OSN’s
por: Uppada, Santosh Kumar, et al.
Publicado: (2022)

Beginning Xamarin development for the Mac: create iOS, watchOS, and Apple tvOS apps with Xamarin.iOS and Visual Studio for Mac
por: Borycki, Dawid
Publicado: (2017)

Beginning Xamarin development for the Mac: create iOS, watchOS, and Apple tvOS apps with Xamarin.iOS and Visual Studio for Mac
por: Borycki, Dawid
Publicado: (2018)

The OsNAC24‐OsNAP protein complex activates OsGBSSI and OsSBEI expression to fine‐tune starch biosynthesis in rice endosperm
por: Jin, Su‐Kui, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_e5np5kt24ormdfajktpj20dekq