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Synthesis of Fluorinated Amide Derivatives via a Radical N-Perfluoroalkylation–Defluorination Pathway

[Image: see text] A one-pot approach to fluorinated hydroxamic acid, amide, and thioamide derivatives is reported. The reaction proceeds via an N-perfluoroalkylation of nitrosoarenes with perfluoroalkanesulfinates, resulting in labile N-perfluoroalkylated hydroxylamines. By the addition of suitable...

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Detalles Bibliográficos
Autores principales: Zheng, Zhiyao, van der Werf, Angela, Deliaval, Marie, Selander, Nicklas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7311088/
https://www.ncbi.nlm.nih.gov/pubmed/32208612
http://dx.doi.org/10.1021/acs.orglett.0c00768