Controlling J-Aggregates Formation and Chirality Induction through Demetallation of a Zinc(II) Water Soluble Porphyrin

Under acidic conditions and at high ionic strength, the zinc cation is removed from its metal complex with 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS(4)) thus leading to the diacid free porphyrin, that subsequently self-organize into J-aggregates. The kinetics of the demetallation step an...

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Detalles Bibliográficos
Autores principales: Occhiuto, Ilaria Giuseppina, Castriciano, Maria Angela, Trapani, Mariachiara, Zagami, Roberto, Romeo, Andrea, Pasternack, Robert F., Monsù Scolaro, Luigi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7313071/
https://www.ncbi.nlm.nih.gov/pubmed/32503280
http://dx.doi.org/10.3390/ijms21114001

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7313071/
https://www.ncbi.nlm.nih.gov/pubmed/32503280
http://dx.doi.org/10.3390/ijms21114001

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