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Azaruthena(II)‐bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)‐catalyzed Alkyne Annulations

A ruthenium‐catalyzed electrochemical dehydrogenative annulation reaction of imidazoles with alkynes has been established, enabling the preparation of various bridgehead N‐fused [5,6]‐bicyclic heteroarenes through regioselective electrochemical C−H/N−H annulation without chemical metal oxidants. Nov...

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Detalles Bibliográficos
Autores principales: Yang, Long, Steinbock, Ralf, Scheremetjew, Alexej, Kuniyil, Rositha, Finger, Lars H., Messinis, Antonis M., Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317209/
https://www.ncbi.nlm.nih.gov/pubmed/32129528
http://dx.doi.org/10.1002/anie.202000762