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Tricoordinate Coinage Metal Complexes with a Redox‐Active Tris‐(Ferrocenyl)triazine Backbone Feature Triazine–Metal Interactions
2,4,6‐Tris(1‐diphenylphosphanyl‐1’‐ferrocenylene)‐1,3,5‐triazine (1) coordinates all three coinage metal(I) ions in a 1:1 tridentate coordination mode. The C(3)‐symmetric coordination in both solid state and solution is stabilised by an uncommon cation–π interaction between the triazine core and the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317378/ https://www.ncbi.nlm.nih.gov/pubmed/32022973 http://dx.doi.org/10.1002/chem.202000226 |