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Small Gold(I) and Gold(I)–Silver(I) Clusters by C−Si Auration
Auration of o‐trimethylsilyl arylphosphines leads to the formation of gold and gold–silver clusters with ortho‐metalated phosphines displaying 3c–2e Au−C−M bonds (M=Au/Ag). Hexagold clusters [Au(6)L(4)](X)(2) are obtained by reaction of (L−TMS)AuCl with AgX, whereas reaction with AgX and Ag(2)O lead...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317441/ https://www.ncbi.nlm.nih.gov/pubmed/32236985 http://dx.doi.org/10.1002/chem.202001509 |