Scope and Limitations of the s‐Block Metal‐Mediated Pudovik Reaction

The hydrophosphorylation of phenylacetylene with di(aryl)phosphane oxides Ar(2)P(O)H (Pudovik reaction) yields E/Z‐isomer mixtures of phenylethenyl‐di(aryl)phosphane oxides (1). Alkali and alkaline‐earth metal di(aryl)phosphinites have been studied as catalysts for this reaction with increasing acti...

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Detalles Bibliográficos
Autores principales: Fener, Benjamin E., Schüler, Philipp, Ueberschaar, Nico, Bellstedt, Peter, Görls, Helmar, Krieck, Sven, Westerhausen, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317549/
https://www.ncbi.nlm.nih.gov/pubmed/32027050
http://dx.doi.org/10.1002/chem.201905565

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317549/
https://www.ncbi.nlm.nih.gov/pubmed/32027050
http://dx.doi.org/10.1002/chem.201905565

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