Cargando…
Salts of HCN‐Cyanide Aggregates: [CN(HCN)(2)](−) and [CN(HCN)(3)](−)
Although pure hydrogen cyanide can spontaneously polymerize or even explode, when initiated by small amounts of bases (e.g. CN(−)), the reaction of liquid HCN with [WCC]CN (WCC=weakly coordinating cation=Ph(4)P, Ph(3)PNPPh(3)=PNP) was investigated. Depending on the cation, it was possible to extract...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317722/ https://www.ncbi.nlm.nih.gov/pubmed/32027458 http://dx.doi.org/10.1002/anie.201915206 |