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“Anti‐Electrostatic” Halogen Bonding

Halogen bonding is often described as being driven predominantly by electrostatics, and thus adducts between anionic halogen bond (XB) donors (halogen‐based Lewis acids) and anions seem counterintuitive. Such “anti‐electrostatic” XBs have been predicted theoretically but for organic XB donors, there...

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Detalles Bibliográficos
Autores principales: Holthoff, Jana M., Engelage, Elric, Weiss, Robert, Huber, Stefan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317790/
https://www.ncbi.nlm.nih.gov/pubmed/32227661
http://dx.doi.org/10.1002/anie.202003083