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High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf(4)N(20)⋅N(2), WN(8)⋅N(2), and Os(5)N(28)⋅3 N(2) with Polymeric Nitrogen Linkers
Polynitrides are intrinsically thermodynamically unstable at ambient conditions and require peculiar synthetic approaches. Now, a one‐step synthesis of metal–inorganic frameworks Hf(4)N(20)⋅N(2), WN(8)⋅N(2), and Os(5)N(28)⋅3 N(2) via direct reactions between elements in a diamond anvil cell at press...
Autores principales: | , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317814/ https://www.ncbi.nlm.nih.gov/pubmed/32212190 http://dx.doi.org/10.1002/anie.202002487 |