High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf(4)N(20)⋅N(2), WN(8)⋅N(2), and Os(5)N(28)⋅3 N(2) with Polymeric Nitrogen Linkers

Polynitrides are intrinsically thermodynamically unstable at ambient conditions and require peculiar synthetic approaches. Now, a one‐step synthesis of metal–inorganic frameworks Hf(4)N(20)⋅N(2), WN(8)⋅N(2), and Os(5)N(28)⋅3 N(2) via direct reactions between elements in a diamond anvil cell at press...

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Detalles Bibliográficos
Autores principales: Bykov, Maxim, Chariton, Stella, Bykova, Elena, Khandarkhaeva, Saiana, Fedotenko, Timofey, Ponomareva, Alena V., Tidholm, Johan, Tasnádi, Ferenc, Abrikosov, Igor A., Sedmak, Pavel, Prakapenka, Vitali, Hanfland, Michael, Liermann, Hanns‐Peter, Mahmood, Mohammad, Goncharov, Alexander F., Dubrovinskaia, Natalia, Dubrovinsky, Leonid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317814/
https://www.ncbi.nlm.nih.gov/pubmed/32212190
http://dx.doi.org/10.1002/anie.202002487

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