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B−B Bond Nucleophilicity in a Tetraaryl μ‐Hydridodiborane(4) Anion
The tetraaryl μ‐hydridodiborane(4) anion [2H](−) possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9‐H‐9‐borafluorene (HBFlu) furnishes the B(3) cluster K[3], with a triangular boron core linked through two BHB two‐electron, three‐center bonds and one electron‐preci...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317828/ https://www.ncbi.nlm.nih.gov/pubmed/32058652 http://dx.doi.org/10.1002/anie.202000292 |