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B−B Bond Nucleophilicity in a Tetraaryl μ‐Hydridodiborane(4) Anion

The tetraaryl μ‐hydridodiborane(4) anion [2H](−) possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9‐H‐9‐borafluorene (HBFlu) furnishes the B(3) cluster K[3], with a triangular boron core linked through two BHB two‐electron, three‐center bonds and one electron‐preci...

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Detalles Bibliográficos
Autores principales:	Trageser, Timo, Bolte, Michael, Lerner, Hans‐Wolfram, Wagner, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317828/ https://www.ncbi.nlm.nih.gov/pubmed/32058652 http://dx.doi.org/10.1002/anie.202000292

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