Unusual Racemization of Tertiary P‐Chiral Ferrocenyl Phosphines

Tertiary phosphines are generally known to withstand inversion under moderate conditions. In this work, a remarkable racemization process of three P‐chiral ferrocenyl phosphines is reported. Subjected to conventional column chromatography as highly enantioenriched compounds, they greatly experienced...

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Detalles Bibliográficos
Autores principales: Popp, John, Hanf, Schirin, Hey‐Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317868/
https://www.ncbi.nlm.nih.gov/pubmed/32048370
http://dx.doi.org/10.1002/chem.202000218

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317868/
https://www.ncbi.nlm.nih.gov/pubmed/32048370
http://dx.doi.org/10.1002/chem.202000218

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