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Unusual Racemization of Tertiary P‐Chiral Ferrocenyl Phosphines
Tertiary phosphines are generally known to withstand inversion under moderate conditions. In this work, a remarkable racemization process of three P‐chiral ferrocenyl phosphines is reported. Subjected to conventional column chromatography as highly enantioenriched compounds, they greatly experienced...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317868/ https://www.ncbi.nlm.nih.gov/pubmed/32048370 http://dx.doi.org/10.1002/chem.202000218 |