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Synthesis and Application of a Perfluorinated Ammoniumyl Radical Cation as a Very Strong Deelectronator

The perfluorinated dihydrophenazine derivative (perfluoro‐5,10‐bis(perfluorophenyl)‐5,10‐dihydrophenazine) (“phenazine(F)”) can be easily transformed to a stable and weighable radical cation salt by deelectronation (i.e. oxidation) with Ag[Al(OR(F))(4)]/ Br(2) mixtures (R(F)=C(CF(3))(3)). As an inno...

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Detalles Bibliográficos
Autores principales: Schorpp, Marcel, Heizmann, Tim, Schmucker, Maximillian, Rein, Stephan, Weber, Stefan, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317951/
https://www.ncbi.nlm.nih.gov/pubmed/32187797
http://dx.doi.org/10.1002/anie.202002768