Enantiocomplementary Epoxidation Reactions Catalyzed by an Engineered Cofactor‐Independent Non‐natural Peroxygenase

Peroxygenases are heme‐dependent enzymes that use peroxide‐borne oxygen to catalyze a wide range of oxyfunctionalization reactions. Herein, we report the engineering of an unusual cofactor‐independent peroxygenase based on a promiscuous tautomerase that accepts different hydroperoxides (t‐BuOOH and...

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Detalles Bibliográficos
Autores principales: Xu, Guangcai, Crotti, Michele, Saravanan, Thangavelu, Kataja, Kim M., Poelarends, Gerrit J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317984/
https://www.ncbi.nlm.nih.gov/pubmed/32160395
http://dx.doi.org/10.1002/anie.202001373

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317984/
https://www.ncbi.nlm.nih.gov/pubmed/32160395
http://dx.doi.org/10.1002/anie.202001373

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