An Unusual and Facile Synthetic Route to Alumoles

Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N‐chelate ligand and R=organic group) with B(C(6)F(5))(3) proceeds through an intermediate with Al⋅⋅⋅η(2)‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐con...

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Detalles Bibliográficos
Autores principales: Li, Jiancheng, Wu, Peng, Jiang, Wenjun, Li, Bin, Wang, Binju, Zhu, Hongping, Roesky, Herbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318123/
https://www.ncbi.nlm.nih.gov/pubmed/32160361
http://dx.doi.org/10.1002/anie.202000899

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318123/
https://www.ncbi.nlm.nih.gov/pubmed/32160361
http://dx.doi.org/10.1002/anie.202000899

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