An Unusual and Facile Synthetic Route to Alumoles

Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N‐chelate ligand and R=organic group) with B(C(6)F(5))(3) proceeds through an intermediate with Al⋅⋅⋅η(2)‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐con...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Jiancheng, Wu, Peng, Jiang, Wenjun, Li, Bin, Wang, Binju, Zhu, Hongping, Roesky, Herbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318123/
https://www.ncbi.nlm.nih.gov/pubmed/32160361
http://dx.doi.org/10.1002/anie.202000899
_version_ 1783550772812709888
author Li, Jiancheng
Wu, Peng
Jiang, Wenjun
Li, Bin
Wang, Binju
Zhu, Hongping
Roesky, Herbert W.
author_facet Li, Jiancheng
Wu, Peng
Jiang, Wenjun
Li, Bin
Wang, Binju
Zhu, Hongping
Roesky, Herbert W.
author_sort Li, Jiancheng
collection PubMed
description Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N‐chelate ligand and R=organic group) with B(C(6)F(5))(3) proceeds through an intermediate with Al⋅⋅⋅η(2)‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐containing heterocycles. The synthetic process is described, and the characterization of compounds and computational calculations were carried out. Furthermore, alumoles 2 and 4 exhibit an aggregation‐induced emission (AIE) of the bright yellow fluorescence.
format Online
Article
Text
id pubmed-7318123
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-73181232020-06-29 An Unusual and Facile Synthetic Route to Alumoles Li, Jiancheng Wu, Peng Jiang, Wenjun Li, Bin Wang, Binju Zhu, Hongping Roesky, Herbert W. Angew Chem Int Ed Engl Communications Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N‐chelate ligand and R=organic group) with B(C(6)F(5))(3) proceeds through an intermediate with Al⋅⋅⋅η(2)‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐containing heterocycles. The synthetic process is described, and the characterization of compounds and computational calculations were carried out. Furthermore, alumoles 2 and 4 exhibit an aggregation‐induced emission (AIE) of the bright yellow fluorescence. John Wiley and Sons Inc. 2020-04-23 2020-06-15 /pmc/articles/PMC7318123/ /pubmed/32160361 http://dx.doi.org/10.1002/anie.202000899 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Li, Jiancheng
Wu, Peng
Jiang, Wenjun
Li, Bin
Wang, Binju
Zhu, Hongping
Roesky, Herbert W.
An Unusual and Facile Synthetic Route to Alumoles
title An Unusual and Facile Synthetic Route to Alumoles
title_full An Unusual and Facile Synthetic Route to Alumoles
title_fullStr An Unusual and Facile Synthetic Route to Alumoles
title_full_unstemmed An Unusual and Facile Synthetic Route to Alumoles
title_short An Unusual and Facile Synthetic Route to Alumoles
title_sort unusual and facile synthetic route to alumoles
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318123/
https://www.ncbi.nlm.nih.gov/pubmed/32160361
http://dx.doi.org/10.1002/anie.202000899
work_keys_str_mv AT lijiancheng anunusualandfacilesyntheticroutetoalumoles
AT wupeng anunusualandfacilesyntheticroutetoalumoles
AT jiangwenjun anunusualandfacilesyntheticroutetoalumoles
AT libin anunusualandfacilesyntheticroutetoalumoles
AT wangbinju anunusualandfacilesyntheticroutetoalumoles
AT zhuhongping anunusualandfacilesyntheticroutetoalumoles
AT roeskyherbertw anunusualandfacilesyntheticroutetoalumoles
AT lijiancheng unusualandfacilesyntheticroutetoalumoles
AT wupeng unusualandfacilesyntheticroutetoalumoles
AT jiangwenjun unusualandfacilesyntheticroutetoalumoles
AT libin unusualandfacilesyntheticroutetoalumoles
AT wangbinju unusualandfacilesyntheticroutetoalumoles
AT zhuhongping unusualandfacilesyntheticroutetoalumoles
AT roeskyherbertw unusualandfacilesyntheticroutetoalumoles

Ejemplares similares