Cargando…
An Unusual and Facile Synthetic Route to Alumoles
Reaction of the aluminum dialkynyl LAl(CCR)(2) (L=N,N‐chelate ligand and R=organic group) with B(C(6)F(5))(3) proceeds through an intermediate with Al⋅⋅⋅η(2)‐C≡C side‐on coordination to form the alumoles (2, 4, 6). A distinctive reaction pattern indicates a new facile synthetic route to aluminum‐con...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318123/ https://www.ncbi.nlm.nih.gov/pubmed/32160361 http://dx.doi.org/10.1002/anie.202000899 |