Opening up the Valence Shell: A T‐Shaped Iron(I) Metalloradical and Its Potential for Atom Abstraction

A thermally stable, T‐shaped, d(7) high‐spin iron(I) complex was obtained by reduction of a PNP‐supported ferrous chloride. Paramagnetic NMR spectroscopy combined with DFT modeling was used to analyze the electronic structure of the coordinatively highly unsaturated complex. The metalloradical chara...

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Detalles Bibliográficos
Autores principales: Ott, Jonas C., Wadepohl, Hubert, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318345/
https://www.ncbi.nlm.nih.gov/pubmed/32196900
http://dx.doi.org/10.1002/anie.202003118

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318345/
https://www.ncbi.nlm.nih.gov/pubmed/32196900
http://dx.doi.org/10.1002/anie.202003118

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