Interplay of Electronic and Steric Effects to Yield Low‐Temperature CO Oxidation at Metal Single Sites in Defect‐Engineered HKUST‐1

In contrast to catalytically active metal single atoms deposited on oxide nanoparticles, the crystalline nature of metal‐organic frameworks (MOFs) allows for a thorough characterization of reaction mechanisms. Using defect‐free HKUST‐1 MOF thin films, we demonstrate that Cu(+)/Cu(2+) dimer defects,...

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Detalles Bibliográficos
Autores principales: Wang, Weijia, Sharapa, Dmitry I., Chandresh, Abhinav, Nefedov, Alexei, Heißler, Stefan, Heinke, Lars, Studt, Felix, Wang, Yuemin, Wöll, Christof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318571/
https://www.ncbi.nlm.nih.gov/pubmed/32196128
http://dx.doi.org/10.1002/anie.202000385

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318571/
https://www.ncbi.nlm.nih.gov/pubmed/32196128
http://dx.doi.org/10.1002/anie.202000385

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