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The Macrocycle versus Chain Competition in On‐Surface Polymerization: Insights from Reactions of 1,3‐Dibromoazulene on Cu(111)

Ring/chain competition in oligomerization reactions represents a long‐standing topic of synthetic chemistry and was treated extensively for solution reactions but is not well‐understood for the two‐dimensional confinement of surface reactions. Here, the kinetic and thermodynamic principles of ring/c...

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Detalles Bibliográficos
Autores principales: Krug, Claudio K., Nieckarz, Damian, Fan, Qitang, Szabelski, Paweł, Gottfried, J. Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7318695/
https://www.ncbi.nlm.nih.gov/pubmed/32031714
http://dx.doi.org/10.1002/chem.202000486