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Photoexcitation of Ge(9)(−) Clusters in THF: New Insights into the Ultrafast Relaxation Dynamics and the Influence of the Cation

We present a comprehensive femtosecond (fs) transient absorption study of the [Ge(9)(Hyp)(3)](−) (Hyp = Si(SiMe(3))(3)) cluster solvated in tetrahydrofuran (THF) with special emphasis on intra- and intermolecular charge transfer mechanisms which can be tuned by exchange of the counterion and by dime...

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Detalles Bibliográficos
Autores principales: Michenfelder, Nadine C., Gienger, Christian, Dilanas, Melina, Schnepf, Andreas, Unterreiner, Andreas-Neil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7321105/
https://www.ncbi.nlm.nih.gov/pubmed/32517154
http://dx.doi.org/10.3390/molecules25112639