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Site-Selective Modification of a Porpholactone—Selective Synthesis of 12,13- and 17,18-Dihydroporpholactones

The reaction of meso-tetrakis(pentafluorophenyl)porpholactone with azomethine ylides and nitrones affords pyrrolidine-fused and isoxazolidine-fused dihydroporpholactones that display, respectively, isobacteriochlorin- and chlorin-type UV–Vis spectra. These reactions are site-selective, yielding, res...

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Detalles Bibliográficos
Autores principales: Cerqueira, Ana F. R., Snarskis, Gustautas, Zurauskas, Jonas, Guieu, Samuel, Paz, Filipe A. Almeida, Tomé, Augusto C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7321334/
https://www.ncbi.nlm.nih.gov/pubmed/32517216
http://dx.doi.org/10.3390/molecules25112642