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“Canopy Catalysts” for Alkyne Metathesis: Molybdenum Alkylidyne Complexes with a Tripodal Ligand Framework

[Image: see text] A new family of structurally well-defined molybdenum alkylidyne catalysts for alkyne metathesis, which is distinguished by a tripodal trisilanolate ligand architecture, is presented. Complexes of type 1 combine the virtues of previous generations of silanolate-based catalysts with...

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Detalles Bibliográficos
Autores principales: Hillenbrand, Julius, Leutzsch, Markus, Yiannakas, Ektoras, Gordon, Christopher P., Wille, Christian, Nöthling, Nils, Copéret, Christophe, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7322728/
https://www.ncbi.nlm.nih.gov/pubmed/32463684
http://dx.doi.org/10.1021/jacs.0c04742